哒螨灵在苹果和土壤上残留以及降解行为研究

本研究建立了基于高效液相色谱为基础的哒螨灵分析方法,并对哒螨灵在安徽淮北和陕西咸阳两地苹果上的消解和残留行为进行了研究,同时还考察了哒螨灵在两地土壤中的降解和残留行为．哒螨灵在苹果中的消解动态方程：陕西咸阳为C=0．4007e^-0.1535t,半衰期T1/2=4．5天;安徽淮北=0．1096e^-0.1464t,半衰期T1/2=4．7天;在土壤中的消解动态方程：陕西咸阳为C=0．7978e^0.1218t,半衰期T1/2=5．7天;安徽淮北C=1．4024e^-0.0912t,半衰期T1/2=7．6天．在推荐使用高剂量和推荐高剂量1．5倍情况下,施药1-2次,末次药后7天,哒螨灵在苹果中的残留为0．02～0．14mg／kg;药后14天为0．01—0．12mg／kg．试验结果表明,药后7天,苹果中哒螨灵的残留量低于2mg／kg,用药次数1-2次,每次间隔7天的情况下,在苹果上的安全间隔期可定为7天．     

Residue integrals and Waring’s formulas for algebraic or even transcendental systems

The present article is focused on the study of a special class of systems of non-linear transcendental equations for which classical algebraic and symbolic methods are inapplicable. For the purpose of study of such systems we develop a method for computing residue integrals with integration over certain cycles. We describe conditions under which the mentioned residue integrals coincide with power sums of the inverses to the roots of a system of equations (i.e. multidimensional Waring’s formulas). Based on this, we develop an algorithm that computes such power sums without computing the roots. As an application of the suggested method, we consider a problem of finding sums of multi-variable number series.     

多元络合物光度法测定冶炼残渣中痕量铟

本文研究了InI-4与碱性染料反应形成多元离子缔合物用于痕量铟的测定.探讨了酸度、温度及表面活性剂对形成多元配合物反应的影响,比较了单显色剂(乙基罗丹明B)与多显色剂(乙基罗丹明B-丁基罗丹明B)的测定结果,单显色剂测定竖罐炼锌焦结物和蒸馏电吸尘焦结物中铟含量的结果分别为2.49 μg/g(RSD为4.72%,n=4)和0.920 μg/g(RSD为4.94%,n=4);双显色剂体系测定竖罐炼锌焦结物和蒸馏电吸尘焦结物中铟含量的结果分别为2.50 μg/g(RSD为1.37%,n=4)和0.98 μg/g(RSD为1.73%,n=4).方法可用于冶炼残渣中铟的测定.     

Signal processing to evaluate parameters affecting SPE for multi‐residue analysis of personal care products

This paper discusses the development of a comprehensive method for the simultaneous analysis of personal care products (PCPs) based on SPE and GC‐MS. The method was developed on 29 target compounds to represent PCPs belonging to different chemical classes: surfactants in detergents (alkyl benzenes), fragrances in cosmetics (nitro and polycyclic musks), antioxidants and preservatives (phenols), plasticizers (phthalates) displaying a wide range of volatility, polarity, water solubility. In addition to the conventional C₁₈ stationary phase, a surface modified styrene divinylbenzene polymeric phase (Strata^TM X SPE cartridge) has been investigated as suitable for the simultaneous extraction of several PCPs with polar and non‐polar characteristics. For both sorbents different solvent compositions and eluting conditions were tested and compared in order to achieve high extraction efficiency for as many sample components as possible. Comparison of the behavior of the two cartridges reveals that, overall, Strata‐X provides better efficiency with extraction recovery higher than 70% for most of the PCPs investigated. The best results were obtained under the following operative conditions: an evaporation temperature of 40°C, elution on Strata‐X cartridge using a volume of 15 mL of ethyl acetate (EA) as solvent and operating with slow flow rate (–10 KPa). In addition to the conventional method based on peak integration, a chemometric approach based on the computation of the experimental autocovariance function (EACVF_tot) was applied to the complex GC‐MS signal: the percentage recovery and information on peak abundance distribution can be evaluated for each procedure step. The PC‐based signal processing proved very helpful in assisting the development of the analytical procedure, since it saves labor and time and increases result reliability in handling GC complex signals.     

Chow-Witt groups and Grothendieck-Witt groups of regular schemes

Let A be a noetherian commutative Z[1/2]-algebra of Krull dimension d and let P be a projective A-module of rank d. We use derived Grothendieck-Witt groups and Euler classes to detect some obstructions for P to split off a free factor of rank one. If d?3, we show that the vanishing of its Euler class in the corresponding Grothendieck-Witt group is a necessary and sufficient condition for P to have a free factor of rank one. If d is odd, we also get some results in that direction. If A is regular, we show that the Chow-Witt groups defined by Morel and Barge appear naturally as some homology groups of a Gersten-type complex in Grothendieck-Witt theory. From this, we deduce that if d=3 then the vanishing of the Euler class of P in the corresponding Chow-Witt group is a necessary and sufficient condition for P to have a free factor of rank one.     

Hopf algebras of primitive Lie pseudogroups and Hopf cyclic cohomology

We associate to each infinite primitive Lie pseudogroup a Hopf algebra of ‘transverse symmetries,’ by refining a procedure due to Connes and the first author in the case of the general pseudogroup. The affiliated Hopf algebra can be viewed as a ‘quantum group’ counterpart of the infinite-dimensional primitive Lie algebra of the pseudogroup. It is first constructed via its action on the étale groupoid associated to the pseudogroup, and then realized as a bicrossed product of a universal enveloping algebra by a Hopf algebra of regular functions on a formal group. The bicrossed product structure allows to express its Hopf cyclic cohomology in terms of a bicocyclic bicomplex analogous to the Chevalley-Eilenberg complex. As an application, we compute the relative Hopf cyclic cohomology modulo the linear isotropy for the Hopf algebra of the general pseudogroup, and find explicit cocycle representatives for the universal Chern classes in Hopf cyclic cohomology. As another application, we determine all Hopf cyclic cohomology groups for the Hopf algebra associated to the pseudogroup of local diffeomorphisms of the line.     

Bandwidth packing with priority classes

The bandwidth packing problem is defined as the selection and routing of messages from a given list of messages with prespecified requirements on demand for bandwidth. The messages have to be routed over a network with given topology so that the generated revenue is maximized. Messages to be routed are classified into two priority classes. An integer programming based formulation of this problem is proposed and a Lagrangean relaxation based methodology is described for solving this problem. A general purpose heuristic is then developed for generating feasible solutions of good quality. Several numerical experiments are conducted using a number of problem parameters such as number of messages, ratio of messages for lower and higher priority classes, capacity of links, and demand distribution of messages belonging to different classes and high quality solutions to the priority bandwidth packing problem are generated under the different situations.     

Optimal server resource reservation policies for priority classes of users under cyclic non-homogeneous markov modeling

Resource availability optimization is studied on a server–client system where different users are partitioned into priority classes. The aim is to provide higher resource availability according to the priority of each class. For this purpose, resource reservation is modeled by a homogeneous continuous time Markov chain (CTMC), but also by a cyclic non-homogeneous Markov chain (CNHMC) as there is a cyclic behavior of the users’ requests for resources. The contribution of the work presented consists in the formulation of a multiobjective optimization problem for both the above cases that aims to determine the optimal resource reservation policy providing higher levels of resource availability for all classes. The optimization problem is solved either with known methods or with a proposed kind of heuristic algorithm. Finally, explicit generalized approximate inverse preconditioning methods are adopted for solving efficiently sparse linear systems that are derived, in order to compute resource availability.     

高效液相色谱柱后衍生测定鸡组织中甲基盐霉素残留量

建立了鸡组织中甲基盐霉素的高效液相色谱柱后衍生化分析方法.样品经异辛烷提取,离心后上层有机相过硅胶固相萃取小柱,洗脱液浓缩后用V(甲醇)∶ V(水)=90∶ 10混合液溶解.采用Inertsil ODS-3 C18柱,以V(甲醇): V(乙酸)∶ V(水)=94∶ 3∶ 3为流动相,香草醛为衍生剂进行高效液相色谱柱后衍生分析,520 nm检测,外标法定量.方法检出限为6 μg/kg; 定量限为20 μg/kg; 添加浓度在20～1800 μg/kg范围内,平均添加回收率为76.4%～93.1%; 批内相对标准偏差(RSD)在2.6%～8.9%之间; 批间相对标准偏差(RSD)在4.7%～9.7%之间.样品浓度在0.07～10.0 mg/L范围内与峰面积呈良好的线性关系,r>0.9993.     

超高效液相色谱-串联质谱法测定牛奶和奶粉中6种聚醚类抗生素残留量

建立了用于检测牛奶和奶粉中拉沙洛菌素、莫能菌素、尼日利亚菌素、盐霉素、甲基盐霉素和马杜霉素铵6种聚醚类抗生素残留量的超高效液相色谱-串联质谱分析方法.用乙腈提取样品中的聚醚类抗生素,提取液经HLB固相萃取柱净化,采用超高效液相色谱分离,以电喷雾离子源正离子多反应监测模式进行质谱分析.6种抗生素在0.5～100.0 μg/L范围内均呈线性,相关系数r>0.99.在空白样品中添加6种聚醚类抗生素的回收率均在74.0%～98.5%之间; 精密度(RSD)4.8%～17.2%.牛奶中6种聚醚类抗生素检出限均为0.2 μg/L;奶粉中6种聚醚类抗生素检出限均为1.6 μg/kg.